Most chemistry journals use numbered citation styles, with all of the references appearing at the end of the article in a References section. However, there are some that place the references at the bottom of the page they occur on, as footnotes. This is a bit more awkward to achieve than a simple section, but as biblatex has all of the citation data available from the start of a document I thought it should be easy to do.

It turns out that biblatex has the very handy \footfullcite macro, which nearly does what is needed. This macro will print the reference as a footnote, but uses LaTeX’s footnote numbering system to do this. The result is that repeating citations, compressing several citations into a range and so on is not so easy. In the end, I decided to drop Philipp Lehman (the author of biblatex) an e-mail for some guidance. He came back with two approaches, one for citations in the text and one for superscript citations:

\documentclass{article}
\usepackage[style=numeric-comp]{biblatex}
\bibliography{biblatex-examples}
\makeatletter

\ExecuteBibliographyOptions{citetracker,sorting=none}

\DeclareCiteCommand{\notefullcite}[\mkbibbrackets]
  {\usebibmacro{cite:init}%
   \usebibmacro{prenote}}
  {\usebibmacro{citeindex}%
   \usebibmacro{notefullcite}%
   \usebibmacro{cite:comp}}
  {}
  {\usebibmacro{cite:dump}%
   \usebibmacro{postnote}}

\newbibmacro*{notefullcite}{%
  \ifciteseen
    {}
    {\footnotetext[\thefield{labelnumber}]{%
       \usedriver{}{\thefield{entrytype}}.}}}
\DeclareCiteCommand{\superfullcite}[\cbx@superscript]%
  {\usebibmacro{cite:init}%
   \let\multicitedelim=\supercitedelim
   \iffieldundef{prenote}
     {}
     {\BibliographyWarning{Ignoring prenote argument}}%
   \iffieldundef{postnote}
     {}
     {\BibliographyWarning{Ignoring postnote argument}}}
  {\usebibmacro{citeindex}%
   \usebibmacro{superfullcite}%
   \usebibmacro{cite:comp}}
  {}
  {\usebibmacro{cite:dump}}

\newbibmacro*{superfullcite}{%
  \ifciteseen
    {}
    {\xappto\cbx@citehook{%
       \noexpand\footnotetext[\thefield{labelnumber}]{%
         \fullcite{\thefield{entrykey}}.}}}}

\newrobustcmd{\cbx@superscript}[1]{%
  \mkbibsuperscript{#1}%
  \cbx@citehook
  \global\let\cbx@citehook=\empty}
\let\cbx@citehook=\empty

\makeatother
\begin{document}

Some filler text \notefullcite{cotton}, then some more text
\notefullcite{hammond}. Perhaps some more text and the same
citation again \notefullcite{hammond}. Yet another one
\notefullcite{knuth:ct:a}. Now all again
\notefullcite{cotton,hammond,knuth:ct:a}.

Some filler text,\superfullcite{augustine} then some more
text.\superfullcite{companion} Perhaps some more text and the
same citation again.\superfullcite{companion} Yet another
one.\superfullcite{kastenholz} Now all
again.\superfullcite{augustine,companion,kastenholz}

\end{document}

I might add this to my biblatex styles, but I’ll wait to see if Philipp puts the code or some notes into the biblatex core before I do. I should also point out that if you want footnote citations and other footnotes then you’ll need something like the bigfoot package to do the job. But this is a pretty good place to start from.